Explain how molecular movement causes the pressure exerted by a gas and hence
deduce the relationship,
(N = number of molecules)
**Can u please deduce this??**
err... isn't this in the notes?
Anyway for deduction, you have to imagine a cubic volume of sides d. And we consider only 1 side of the wall.
for a molecule of mass m, it's change in momentum. So, that's mc - (-mc) = 2mc
time taken by a molecule between 2 sides of a wall = 2d / c (distance / speed)
hence, num of collisions per unit time = (N/3)/t = Nc/6d
We take N/3 because there are 3 directions, and we are only considering one direction. It's an average value.
multiply above, you get Nmc²/3d for total change in momentum per unit time.
Remember Newton's 2nd law, force is d(mv)/dt, which means change in momentum per unit time. This means Nmc²/3d is the force on one side of the wall. Thus, pressure = force/area
p = â…“(Nmc²/d) / A
p = â…“(Nmc²/Ad) ============> A*d = V (volume)
p = â…“(Nmc²/V)
(deduced)
btw, c is the root-mean-squared speed... You should use <c> in your workings. I was lazy to type out...
I'm copying these from a study guide
The pressure exerted by an ideal gas could be explained by the motion of the gas molecules as follows: